[1,2-Bis(pyridin-2-ylmethoxy)benzene-κ4 N,O,O′,N′]bis(nitrato-κO)cobalt(II)
نویسندگان
چکیده
In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))], the Co(II) ion is six-coordinated in a distorted octa-hedral environment defined by two O and two N atoms from the ligand and by two O atoms from two nitrate anions. A two-dimensional network parallel to the ab plane is built up by C-H⋯O hydrogen bonds, which link adjacent mol-ecules in the crystal structure.
منابع مشابه
catena-Poly[[bis(nitrato-κO)cobalt(II)]-bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the Co(II) ion is located on an inversion center and is six-coordinated in an octa-hedral environment defined by four N atoms of the pyridine rings and two O atoms of the nitrate anions. The ligands link the Co(II) ions into a linear chain running along [201]. One O atom of the nitrate ligand is disordered over two positions with ...
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In the title compound, [Cu(NO(3))(2)(C(18)H(16)N(2)O(2))], the Cu(II) ion is six-coordinated in a Jahn-Teller-distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from two monodentate nitrate anions.
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In the title compound, [Cd(NO(3))(2)(C(24)H(20)N(2)O(2))], the Cd(II) ion is eight-coordinated by one ligand and two nitrate ions. There are C-H⋯O hydrogen bonds and C-H⋯π inter-actions and π-π inter-actions [centroid-centroid distance = 3.319 (1) Å] in the crystal structure.
متن کاملcatena-Poly[[bis(nitrato-κO)copper(II)]-bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Cu(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the Cu(II) ion lies on an inversion center and is six-coordinated in a Jahn-Teller-distored octa-hedral geometry defined by four N atoms of the pyridine derivative forming a square plane, above and below which are the O atoms of the nitrate anion. The ligand links the metal atoms linto a linear chain running along the a axis. One ...
متن کاملcatena-Poly[[bis(nitrato-κO)cadmium]bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Cd(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the six-coordinated Cd(II) ion is located on an inversion center and has a distorted octa-hedral environment defined by four N atoms from four 1,4-bis-(pyridin-3-ylmeth-oxy)benzene ligands and two O atoms from two nitrate anions. The ligands link the Cd(II) ions into a ribbon-like structure running along [201]. One O atom of the n...
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